Title:	Catalytic reduction of NO with CO over Supported Fe-Based Catalysts
Authors:	Gholami, Fatemeh
Citation:	JIRKOVÁ, Hana ed.; JENÍČEK, Štepán ed. Proceedings PING 2019: modern trends in material engineering: 10.-13.09.2019, Pilsen. 1. vyd. Plzeň: University of West Bohemia, 2019, s. 100. ISBN 978-80-261-0879-5.
Issue Date:	2019
Publisher:	University of West Bohemia
Document type:	konferenční příspěvek conferenceObject
URI:	http://hdl.handle.net/11025/35266
ISBN:	978-80-261-0879-5
Keywords:	odstranění NOx;selektivní katalytická redukce;CO-SCR
Keywords in different language:	NOx removal;selective catalytic reduction;CO-SCR
Abstract in different language:	The catalytic activity of a series of La-Fe catalysts supported on activated carbon was studied for selective catalytic reduction of NO by CO. Increasing the amount of La in the catalyst structure causes an increase in the Fe2+/Fe3+ ratio. The results showed that by increasing the La amount in catalysts, the catalytic activity of the AC-supported catalysts was enhanced because of the synergistic interactions between surface oxygen vacancies and Fe2+ species in the AC-supported catalysts. Due to the high catalytic performance of MnOx, the NOx conversion of Mn@La3-Fe1/AC catalyst was improved to 92.67% at the absence of oxygen at 400 °C. The Mn promoted La3- Fe1/AC catalyst showed the highest NOx conversion of 93.8% at 400 °C in the presence of 10% excess oxygen. Compared with other prepared catalysts, the Mn@La3-Fe1/CNT catalyst showed the highest activity due to the higher Fe2+/Fe3+, which confirmed by XPS analysis. The double exchange behavior of Mn3+ and Mn4+ can increase the number of SOV and increase catalytic redox properties.
Rights:	© University of West Bohemia
Appears in Collections:	Proceedings PING 2019: modern trends in material engineering Konferenční příspěvky / Conference Papers (CTM) Proceedings PING 2019: modern trends in material engineering

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